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:Perovskite nanocrystals as a tunable light-emitting material.
Highly luminescent nanocrystals (NCs) of a perovskite oxide in the form of CsPb(X)Br(3-X) (X = 0-3) are grown by a traditional solution-based synthesis. The size, shapes, and luminescence properties of these NCs are extensively and successfully controlled by varying the reaction conditions. Particularly, the size of the NCs is tunable from 2 to 24 nm as determined by transmission electron microscopy (TEM) analysis. The cubic structure of these NCs has been confirmed by powder X-ray diffraction (XRD) analysis. Photoluminescence (PL) spectroscopy is used to measure the PL emission of these NCs at different excitation wavelengths, and the PL emission is shown to be tunable with the change in excitation wavelength. The PL intensity is maximized when the excitation wavelength is 420 nm and the NCs are smaller (3-5 nm in diameter). As the excitation wavelength is increased above 420 nm, the PL peak shifts to the long wavelength side. TEM results are used to explain the observed PL properties.suser542jm

Posts: 1
Joined: Mar 2017

Jul 17, 2017 – 9:05 am

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